CSS uses ordinal numbering when identifying elements in an ordered collection. For example, :first-child matches the first child element of a parent, @page :first matches the first page, ::first-line matches the first line in a block, and ::first-letter matches the first letter of the first line of a block.
The :nth-child() pseudo-class is a generalization of the :first-child selector, where you read n as the provided number. So :nth-child(1) means 1st child or first-child child,:nth-child(2) means 2nd child, and so forth.
So it is natural that :nth-child(1) selectselects the first child, and it would be highly confusing and illogical if it selected the second child!
CSS uses ordinal numbering because this is how humans naturally talk about such elements. You say the first paragraph of a text, not the zeroth paragraph or paragraph-zero.
The reason you even ask the question is probably because you are a programmer, and many programming languages indexesindex array and list items from 0. The reason for this is that in low level languages like C, an array is really a pointer to the memory address of the first item and the index is an offset relative to this pointer. So array[0] means address of first item, array[1] means address of the first item plus the size of 1 item, i.e. second item and so on.
Many higher-level languages which doesdo not support pointer arithmetic directly have retained the 0-based indexing for consistency and familiarity. For example, all languages with C-derived syntax - including JavaScript, even though arrays in JavaScript are implemented in a completely different way. But this is not at all universal - languages like COBOL, Fortran, Lua, Julia and some Basic's use 1-based indexing. (Visual Basic naturally chose the worst of both worlds by making it configurable.) So it is definitely not like every other language use 0-based indexing. For what itsit's worth, XPath and XQuery also use 1-based indexing.
While most programmers will be familiar with both 1 and 0-based indexing, normal people will naturally count from 1, and CSS is a language designed not just for programmers but for designers and graphic professionals, so it is natural to choose 1-based indexing.