You can get the member method address with class_getMethodImplementation() for example. But this does not help, because you cannot assign a method implementation (basically a function) to a block var. This is, because blocks are not simply function vars, but closures. And closures have a creational context, methods have an object context. That's not the same.
However, there are options to get,what you probably want to get:
Instead of having a block var, use a method implementation var of type IMP. If you execute the method, remember to pass a self pointer and a selector as expected by methods.
You can have a selector var, which stores the selector of the method to be executed. It's type is SEL. Then you can send a message using one method of the -performSelector: family.
You can assign a block to your current ivar, that does nothing else than sending a message with the method's selector. (Which "calls" the desired method.)
If you give more information about your situation, I can add a more detailed solution fitting to your problem.