First of all, you can't just copy a string to a wide character array - everything is going to go berserk on you.
A std::string is built with char, a std::wstring is built with wchar_t. Copying a string to a wchar_t[] is not going to work - you'll get gibberish back. Read up on UTF8 and UTF16 for more info.
That said, as Luchian says, VLAs can't be done in C++ and his heap allocation will do the trick.
However, I must ask why are you doing this? If you're using std::string you shouldn't (almost) ever need to use a character array. I assume you're trying to pass the string to a function that takes a character array/pointer as a parameter - do you know about the .c_str() function of a string that will return a pointer to the contents?