The two lines of code are a function definition and then execution call of that definition with an empty array passed inside. The complexity lies in interpreting what 'this' will point to and why.
To help deduce the value of this I copied content from two links below to MDN's definitions of call and bind.
The bind() function creates a new function (a bound function) with the same function body as the function it is being called on (the bound function's target function) with the this value bound to the first argument of bind(). Your code looks similar to a 'shortcut function' described on the bind page.
var unboundSlice = Array.prototype.slice; // same as "slice" in the previous example
var slice = Function.prototype.call.bind(unboundSlice);
// ...
slice(arguments);
With call, you can assign a different this object when calling an
existing function. this refers to the current object, the calling
object.With call, you can write a method once and then inherit it in
another object, without having to rewrite the method for the new
object.
When toStr is called it passes in an array to bind, of which the this pointer is bound.
With bind(), this can be simplified.
toStr() is a bound function to the call() function of Function.prototype, with the this value set to the toStr() function of Array.prototype. This means that additional call() calls can be eliminated.
In essence, it looks like a shortcut function override to the toString method.