If you mean MySQL is returning an error message (if that's what you mean by "not working for me"), then that's exactly the behavior we would expect.
That SQL syntax is not valid for MySQL.
If you want to delete rows from a table, issue a DELETE statement, e.g.
DELETE FROM mytable WHERE City = 'Barcelone'
If you want to know how many rows were deleted (if the statement doesn't throw an error), immediately follow the DELETE statement (in the same session) with a query:
SELECT ROW_COUNT()
Or the appropriate function in whatever client library you are using.
If the ROW_COUNT() function returns 0, then there were no rows deleted.
There's really no point (in terms of MySQL) in issuing a SELECT to find out if there are rows to be deleted; the DELETE statement itself will figure it out.
If for some reason your use case requires you to check whether there are rows be be deleted, then just run a separate SELECT:
SELECT COUNT(1) FROM mytable WHERE City = 'Barcelone'
Select query is working