There are multiple problems with your code.
test[50] = "9999:STRING OF TEXT";
This is wrong for two reasons.
A) test is an array of char, not an array of char*. So, when you assign a string (a char*) to an element, the address is converted to a char.
B) Element 50 does not exist in your array, and writing to it invokes undefined behavior. You have an array of 50 elements with indices 0...49.
To assign an initial value to your array, all you need do is:
char test[50] = "9999:STRING OF TEXT";
And since test does not need to be modified...
const char *test = "9999:STRING OF TEXT";
If you want to zero an array, the simplest method is:
char test[50] = {0};
Of course, you don't need to if you assign the string properly to begin with, and this is not your problem.
Your string member of the a struct is a char, not a char* (a string), and using the %s format specifier when printing it invokes undefined behavior.
main is defined to return int, not void.
sscanf expects pointers to data to fill in. rec.ref is an int, you need to pass its address, i.e., &rec.ref.
You need to allocate storage for rec.string.
Here is a working example:
#include <stdio.h>
#define STRING_LEN 50
struct a
{
int ref;
char string[STRING_LEN];
} rec;
int main()
{
char test[STRING_LEN] = "9999:STRING OF TEXT";
// note that, in the real world, this may
// be a buffer overflow waiting to happen
sscanf(test, "%d:%[^\n]", &rec.ref, rec.string);
printf("String is:%s, rec is:%d", rec.string, rec.ref);
return 0;
}
#include <stdio.h>