It's not a very good question. The code as presented doesn't compile, and the shortest possible fix is actually to change the function signature to
public int? Add(int? a, int? b)
Addition is supported on nullable integers through lifting: adding null to another value will just yield null. This is almost certainly not what the interviewer was angling for; probably they intended you to treat null as if it was 0, for which a ?? 0 suffices. But maybe they wanted (a + b) ?? 0 instead, which returns 0 if either operand is null.
Well, on second thought, maybe it is a good question, to see if you would ask follow-up questions. The most pertinent one would be: "what do you want this function to do when presented with nulls?"