Not all request headers are available in AngularJS request interceptor's config parameter. other header values are browser settings that are added while constructing the request.
You could use, but i'm not sure it gives you the right language.
var language = window.navigator.userLanguage or
window.navigator.language;
Only the server can see the value of Accept-Language. So i think the best way is to get this value from the server response-body and memorize it in you cookies (name example AcceptLanguageCookie) and after that you can overide the Accept-Language someway like this in your interceptor.
var app = angular.module("app", []);
app.config(["$httpProvider", function($httpProvider) {
// set Accept-Language header on all requests
$httpProvider.defaults.headers.common["Accept-Language"] = $cookies.get("AcceptLanguageCookie");
}]);