The /text() only prints the text immediately under the current tag. So your current code will not print the synonyms since it's under another tag inside the div tag.
You should use //text() to print all texts under the current tag. But this will print ALL texts, including the unnecessary ones.
For your use case, since the synonyms are inside a <span class="text"> tag, you can use this XPath:
//div[@class="relevancy-list"]//span[@class="text"]/text()
which selects all texts found inside a span with class "text" found inside a div with class "relevancy-list".
For input term set, the output using that XPath is:
['firm', 'bent', 'stated', 'specified', 'rooted', 'established', 'confirmed', 'pat', 'immovable', 'obstinate', 'ironclad', 'predetermined', 'intent', 'entrenched', 'appointed', 'regular', 'prescribed', 'determined', 'scheduled', 'fixed', 'settled', 'certain', 'customary', 'decisive', 'definite', 'inveterate', 'pigheaded', 'resolute', 'rigid', 'steadfast', 'stubborn', 'unflappable', 'usual', 'concluded', 'agreed', 'resolved', 'stipulated', 'arranged', 'prearranged', 'dead set on', 'hanging tough', 'locked in', 'set in stone', 'solid as a rock', 'stiff-necked', 'well-set', 'immovable', 'entrenched', 'located', 'solid', 'situate', 'stiff', 'placed', 'stable', 'fixed', 'settled', 'situated', 'rigid', 'strict', 'stubborn', 'unyielding', 'hidebound', 'positioned', 'sited', 'jelled', 'hard and fast', 'deportment', 'comportment', 'fit', 'presence', 'mien', 'hang', 'carriage', 'air', 'turn', 'attitude', 'address', 'demeanor', 'position', 'inclination', 'port', 'posture', 'setting', 'scene', 'scenery', 'flats', 'stage set', u'mise en sc\xe8ne', 'series', 'array', 'lot', 'collection', 'batch', 'crowd', 'cluster', 'gang', 'bunch', 'crew', 'circle', 'body', 'coterie', 'faction', 'company', 'bundle', 'outfit', 'band', 'clique', 'mob', 'kit', 'class', 'clan', 'compendium', 'clutch', 'camp', 'sect', 'push', 'organization', 'clump', 'assemblage', 'pack', 'gaggle', 'rat pack', 'locate', 'head', 'prepare', 'fix', 'introduce', 'turn', 'settle', 'lay', 'install', 'put', 'apply', 'post', 'establish', 'wedge', 'point', 'lock', 'affix', 'direct', 'rest', 'seat', 'station', 'plop', 'spread', 'lodge', 'situate', 'plant', 'park', 'bestow', 'train', 'stick', 'plank', 'arrange', 'insert', 'level', 'plunk', 'mount', 'aim', 'cast', 'deposit', 'ensconce', 'fasten', 'embed', 'anchor', 'make fast', 'make ready', 'zero in', 'appoint', 'name', 'schedule', 'make', 'impose', 'stipulate', 'settle', 'determine', 'establish', 'fix', 'specify', 'designate', 'decree', 'resolve', 'rate', 'conclude', 'price', 'prescribe', 'direct', 'value', 'ordain', 'allocate', 'instruct', 'allot', 'dictate', 'estimate', 'regulate', 'assign', 'arrange', 'lay down', 'agree upon', 'fix price', 'fix', 'stiffen', 'thicken', 'condense', 'jelly', 'clot', 'congeal', 'solidify', 'cake', 'coagulate', 'jell', 'gelatinize', 'crystallize', 'jellify', 'gel', 'become firm', 'gelate', 'drop', 'subside', 'sink', 'vanish', 'dip', 'disappear', 'descend', 'go down', 'initiate', 'begin', 'raise', 'abet', 'provoke', 'instigate', 'commence', 'foment', 'whip up', 'put in motion', 'set on', 'stir up']
Note that you will get the synonyms for all senses of the word.
You might want to loop over the result of //div[@class="relevancy-list"] manually, and extract the //span[@class="text"]/text() for each div found to get the synonyms per sense.