It really depends what you want to do with the data. For most UI widgets and that sort of thing, you'll want to just use the store directly. If you want to get a piece of data from the store for tweaking manually, that's a whole nother story.
store.getRange() will indeed return all of the records from the store, but they are returned as an Array of Record objects. Records contain an attribute called data which is an object containing any properties you defined in the record's config.
Example:
Ext.each(store.getRange(), function (item, idx, a) {
for (var i in item.data) {
console.log(item.data[i])
}
})
That should show you every item in every Record in store
EDIT: Changed my answer to not be totally wrong.