Trying to decrypt a single des encrypted data using this code:
$keyValue ='0123456789abcdef'; //hex value
$encryptedOrderId = '88C10F0B8C084E5F'; //hex value
$binaryEncrypted = hex2bin($encryptedOrderId);
$decodeValueByOnlineTool = '2020202039353538'; // this is hex
$opensslDecrypt = openssl_decrypt( $encryptedOrderId ,'DES-ECB', $keyValue, OPENSSL_RAW_DATA , '' );
var_dump($opensslDecrypt);
The output is false. I do not know what wrong I'm doing.

keyValuein your call toopenssl_decrypt? Did you actually write that code or have you copied it from somewhere without understanding it? I suggest you read the docs foropenssl_decrypt.