How do you know that your function should fit the data and from where do you get the values a,b?
In general, you can shift and scale basic functions, e.g. like log().
So, if you think log(x) is a suitable function to describe your data then try to shift and scale it.
Shift x by x0, shift y by y0 and scale with some factor a.
Altogether:
f(x) = a*log(x-x0) + y0
In the script example below it seems that you don't even need approximate starting values to let the fit converge.
However, the mathematical description of your system should give you the function. Without knowing your system, nobody can tell whether f(x) is an appropriate function to fit your data.
Script:
### fitting a log function
reset session
$Data <<EOD
6.77 0.000165774
8.13 0.00034866
9.48 0.000440373
10.83 0.000473223
16.25 0.000589812
18.28 0.000629904
20.31 0.000661883
EOD
f(x) = a*log(x-x0) + y0
set fit nolog
fit f(x) $Data u 1:2 via a,x0,y0
set key top left
plot $Data u 1:2 w lp pt 7, \
f(x) w l lc "red", \
0.000855*(1 + 0.45*log(x/32.23)) w l dt 3 lc "blue" ti "your guess"
### end of script
Result:
Final set of parameters Asymptotic Standard Error
======================= ==========================
a = 0.000153601 +/- 8.592e-06 (5.594%)
x0 = 6.17491 +/- 0.1102 (1.785%)
y0 = 0.000245976 +/- 1.982e-05 (8.057%)
